2010年3月1日 The direct carbothermal reduction of SiO 2 to Si metal was simulated as a function of mole ratio of SiO 2, SiC and C in the temperature range of 0–3000 °C by using a thermodynamic calculation of Gibb’s free-energy minimization. In the SiO 2 –C system,
Read MoreAbstract. The carbothermic reduction of silicon dioxide at high temperature was studied using a free energy minimization (FEM) program. The stability boundaries of Si (l), SiC
Read More2020年12月10日 In this paper, for the first time, we report evidence of reduced silicon from silica by ultrafast carbothermal reduction using a CO 2 laser beam. A CO 2 laser is
Read More10.1.6.2.1. Carbothermic reduction of silicon dioxide Si MG is produced industrially by a carbothermal reduction of silicon dioxide (SiO 2 ) in electric submerged arc furnaces.
Read MoreCarbothermic reduction is the most widely used process for preparing nitride fuel. The starting material is a dioxide and carbon, and the general reaction is expressed as [I]
Read More2017年8月29日 Carbothermic Reduction of Silicon A Thermodynamic Investigation Dioxide S.G. HUTCHISON, L. S. RICHARDSON, and C.M. WAI The carbothermic reduction of
Read MoreAbstract. Silicon carbide, silicon nitride or silicon monoxide may be produced by carbothermal reduction of silica depending on conditions. The mechanism for the
Read MoreZincothermic reduction of silica to silicon: Make the impossible possible. Huayi YinMuya CaiDihua Wang. Metallothermically reducing silica to nano silicon is an energy-effective
Read More2007年7月1日 Mass-transfer processes during the high-temperature carbothermic reduction of silicon dioxide have been studied using thermodynamic modeling. The
Read MoreAccording to these properties, silicon materials are expected to be useful for bioimaging4,5and for the anode in Li-ion batteries.6Thus far, silicon is mainly obtained
Read MoreDirect Carbothermic Silica Reduction from Purified Silica to Solar-Grade Silicon. Kenji Itaka1*, Takuya Ogasawara1, Abderahmane Boucetta1, Rabie Benioub1, Masatomo Sumiya2, Takuya Hashimoto3, Hideomi Koinuma4, Yasubumi Furuya1. 1 North Japan Research Institute for Sustainable Energy, Hirosaki University, 2-1-3, Matsubara, Aomori,
Read MoreThe carbothermic reduction of silicon dioxide at high temperature was studied using a free energy minimization (FEM) program. The stability boundaries of Si(l), SiC(s), and SiO 2 (l), and the equilibrium compositions of the gaseous species at various pressures, temperatures, and total composition of the system have been calculated based on
Read More2008年8月10日 The carbothermic reduction of NiO, CoO, CuO, MoO3, and the MMoO4 (M = Ni, Co, Cu) molybdates has been studied by thermogravimetry. The results demonstrate that the reactivity of the molybdates with solid carbon, the sequence of reduction reactions, and the composition of reaction intermediates are determined by the reactivity of the
Read More2020年8月1日 In conclusion, the molten salts containing CaCl 2 are usually utilized in electro-reduction of silicon dioxide to silicon due to a larger solubility of O 2– ions which is important in the process. Adding other kinds of molten salts like LiCl\KCL\CsCl can lower the reaction temperature as well as decrease the reduction rate which is beneficial ...
Read MoreSilicon carbide, silicon nitride or silicon monoxide may be produced by carbothermal reduction of silica depending on conditions. The mechanism for the reduction of silica involves a chain reaction, gas-solid scheme. ... K. I. Otsuka and D. Kunii, “Reduction of Powdery Ferric Oxide Mixed with Graphite Particles,” J. Chem. Eng. Japan 2 (1 ...
Read More2016年3月1日 To model the effect of silicon oxide in the carbothermic reduction of alumina system, the following initial molar composition is used: 3-X Al. 2O. 3 + X SiO. 2 + 9-X C,with X ranging from 0 to 3 (1) The above composition is stoichiometric in carbon for all values of X. The calculated recovery of Aluminum in the liquid metal
Read More2011年6月26日 This paper presents a thermodynamic study of the Al-C-O system, a short review on the alumina carbothermic processes developed so far and two novel carbothermic reductions concepts along with ...
Read More2018年2月1日 Abstract. Metallurgical-grade silicon (MG-Si) was successfully produced by carbothermic reduction-smelting of Egyptian quartz using a mixture of carbonaceous materials in a locally made semi-pilot ...
Read More2005年10月12日 The primary carbothermic reactions for the reduction of silica to produce silicon were defined and the reaction kinetics were determined. Most possible reactions between silicon oxide and carbon ...
Read More2018年2月10日 Silicon is traditionally prepared for commercial use by carbothermic reduction of silicon dioxide with carbonaceous reductants in a submerged arc furnace (SAF). We investigated the effect of petroleum coke and coal on the process of silicon production via linear regression (Chen et al., 2016) and studied the effect of different raw materials
Read More2017年8月29日 The carbothermic reduction of silicon dioxide at high temperature was studied using a free energy minimization (FEM) program. The stability boundaries of Si(1), SiC(s), and SiO2(1), and the equi- librium compositions of the gaseous species at various pressures, temperatures, and total composi- tion of the system have been calculated
Read More2023年2月12日 The emission range for the carbothermic reduction of silicon from quartz in the submerged arc furnace is estimated in the literature [2, 3] to be 4.7–5 t CO 2 e/t Si, including the contribution from the carbon electrodes. This number can be reduced by increasing the share of biocarbon among reductants, as this material is considered
Read More2019年12月4日 In this section, experimental procedure for reduction of silica using carbon powder is described. Carbon powders had a high purity (more than 99 %w total carbon, from Merck Company); silica powder (crystalline quartz from Mount Rose, Canada) contained more than 95 %w SiO 2; and Helium gas with 99.999% purity (from Air Products
Read MoreMass-transfer processes during the high-temperature carbothermic reduction of silicon dioxide have been studied using thermodynamic modeling. The chemical vapor transport of silicon carbide has been investigated using SiO 2 + xSiC mixtures—major reaction products in the SiO 2-C system—as examples.Thermodynamic modeling results indicate that the
Read More2011年3月15日 Silicon is produced industrially by carbothermic reduction of silicon dioxide in submerged-arc electric furnaces. Feed materials include a silicon source such as quartz, and a typical reductant blend comprising coke, coal, charcoal, and wood chips. Feed materials are impure, and impurities are carried to a certain extent
Read More2023年6月1日 The resulting carbothermic reduction produces silicon carbide as its end product. The process is not complicated but produces a great deal of CO 2: around 2.4 tons of the greenhouse gas are released for 1 ton of SiC from the carbothermic reduction alone. This is in addition to the enormous power consumption of 7.15 MWh/t, which is required
Read More2021年7月22日 Fly ash is a by-product from burning of coal. Utilization of fly ash by carbothermic reduction is an effective way to recover aluminum, silicon, and iron to enhance product-added value. This work is focused on the phase transformation of Al2O3, SiO2 and Fe2O3 during carbothermic reduction of fly ash in air. A comparative analysis of
Read More2021年8月31日 Metallurgical Grade silicon (MG silicon) is produced in submerged arc furnaces by carbothermic reduction of quartz. The main raw materials are SiO 2 in the form of quartz and carbon materials that consist of coal, coke, charcoal, and woodchips. In this continuous process, the raw materials are fed into a submerged arc furnace (SAF) from
Read More2020年11月1日 The petroleum coke was provided by Tianjing Mingxintai Petrochemical Co. Ltd., China. Fig. 2 illustrates the particle size distribution of the petroleum coke showing a mean particle size of ∼10 μm and a concentrated size distribution in the range of 0.5–30 μm. The fine particles contribute to the high temperature carbothermic reduction of the
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